2003Current Organic ChemistryRequires access

Recent Progresses on the Fixation of Carbon Dioxide

Min Shi, Yu‐Mei Shen

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Abstract

This review introduces the recent progresses on the fixation of carbon dioxide (CO2) including 1) the reactions of carbon dioxide with alcohols in the presence of base; 2) the reactions of carbon dioxide with amines in the presence of base; and 3) the transition metal catalyzed carbon dioxide insertion reactions. In the section of transition metal catalyzed fixation of carbon dioxide, we mainly focus on the catalytic process of carbon dioxide insertion reactions promoted by metal catalysts and the emphasis is put on the preparation of the corresponding carbonates or carbamates from CO2 and their further transformations. Keywords: Carbon Dioxide, carbonates, carbamates

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What this paper is about

This review introduces the recent progresses on the fixation of carbon dioxide (CO2) including 1) the reactions of carbon dioxide with alcohols in the presence of base; 2) the reactions of carbon dioxide with amines in the presence of base; and 3) the transition metal catalyzed carbon dioxide insertion reactions. In the section of transition metal catalyzed fixation of carbon dioxide, we mainly focus on the catalytic process of carbon dioxide insertion reactions promoted by metal catalysts and the emphasis is put on the preparation of the corresponding carbonates or carbamates from CO2 and their further transformations. Keywords: Carbon Dioxide, carbonates, carbamates

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Available abstract

This review introduces the recent progresses on the fixation of carbon dioxide (CO2) including 1) the reactions of carbon dioxide with alcohols in the presence of base; 2) the reactions of carbon dioxide with amines in the presence of base; and 3) the transition metal catalyzed carbon dioxide insertion reactions. In the section of transition metal catalyzed fixation of carbon dioxide, we mainly focus on the catalytic process of carbon dioxide insertion reactions promoted by metal catalysts and the emphasis is put on the preparation of the corresponding carbonates or carbamates from CO2 and their further transformations. Keywords: Carbon Dioxide, carbonates, carbamates

Key concepts: Carbon dioxide, Chemistry, Carbon fixation, Catalysis, Electrochemical reduction of carbon dioxide, Transition metal, Carbon fibers, Inorganic chemistry

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