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Separation of rare earth elements using Ln-EDTA eluent in an anion exchanger

Ki Won, Chan Il Park, Byung Doo Chang, Sung Wook Hong

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Abstract

Chloride form anion exchange resin was used to separate one of the elements from the rare earth mixture using respectable Ln-EDTA eluent. , or complexed with EDTA was passed through the resin column and eluted with a Sm-EDTA solution as an eluent. Here all the rare earth element ions except were passed. Adsorbed in resin was eluted with 1.0 M HCl solution. If La-EDTA solution as an eluent was used to separate lanthanum ions, lanthanum ions were eluted together with other rare earth elements. When Ce-EDTA solution was also used for separation of , it was eluted in the region of other rare earth elements. In the case of Sm-EDTA elution, the elution mechanism was as follows : Absorption : , Sm-EDTA elution : , HCl elution : .

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What this paper is about

Chloride form anion exchange resin was used to separate one of the elements from the rare earth mixture using respectable Ln-EDTA eluent. , or complexed with EDTA was passed through the resin column and eluted with a Sm-EDTA solution as an eluent. Here all the rare earth element ions except were passed. Adsorbed in resin was eluted with 1.0 M HCl solution. If La-EDTA solution as an eluent was used to separate lanthanum ions, lanthanum ions were eluted together with other rare earth elements. When Ce-EDTA solution was also used for separation of , it was eluted in the region of other rare earth elements. In the case of Sm-EDTA elution, the elution mechanism was as follows : Absorption : , Sm-EDTA elution : , HCl elution : .

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Available abstract

Chloride form anion exchange resin was used to separate one of the elements from the rare earth mixture using respectable Ln-EDTA eluent. , or complexed with EDTA was passed through the resin column and eluted with a Sm-EDTA solution as an eluent. Here all the rare earth element ions except were passed. Adsorbed in resin was eluted with 1.0 M HCl solution. If La-EDTA solution as an eluent was used to separate lanthanum ions, lanthanum ions were eluted together with other rare earth elements. When Ce-EDTA solution was also used for separation of , it was eluted in the region of other rare earth elements. In the case of Sm-EDTA elution, the elution mechanism was as follows : Absorption : , Sm-EDTA elution : , HCl elution : .

Key concepts: Elution, Chemistry, Column chromatography, Lanthanum, Ion exchange, Ion-exchange resin, Adsorption, Chloride

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