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Use of a surfactant coacervate phase to extract trichloroethylene from water

WAROPHAT KIMCHUWANIT, John F. Scamehorn, Somchai Osuwan

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Abstract

At temperatures above the cloud point, aqueous nonionic surfactant solutions can separate into two phases: a surfactant-rich coacervate phase and a surfactant-dilute phase. Since the coacervate phase can be a concentrated micellar solution, organic solute tends to concentrate in the coacervate due to solubilization. In this study, up to 90% of trichloroethylene was shown to be extracted into the coacervate phase in one stage. Increasing temperature, surfactant concentration, and added NaCl concentration all improved the fraction of TCE extracted.

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What this paper is about

At temperatures above the cloud point, aqueous nonionic surfactant solutions can separate into two phases: a surfactant-rich coacervate phase and a surfactant-dilute phase. Since the coacervate phase can be a concentrated micellar solution, organic solute tends to concentrate in the coacervate due to solubilization. In this study, up to 90% of trichloroethylene was shown to be extracted into the coacervate phase in one stage. Increasing temperature, surfactant concentration, and added NaCl concentration all improved the fraction of TCE extracted.

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Available abstract

At temperatures above the cloud point, aqueous nonionic surfactant solutions can separate into two phases: a surfactant-rich coacervate phase and a surfactant-dilute phase. Since the coacervate phase can be a concentrated micellar solution, organic solute tends to concentrate in the coacervate due to solubilization. In this study, up to 90% of trichloroethylene was shown to be extracted into the coacervate phase in one stage. Increasing temperature, surfactant concentration, and added NaCl concentration all improved the fraction of TCE extracted.

Key concepts: Coacervate, Pulmonary surfactant, Cloud point, Chemistry, Phase (matter), Aqueous solution, Chromatography, Trichloroethylene

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