Use of a surfactant coacervate phase to extract trichloroethylene from water
WAROPHAT KIMCHUWANIT, John F. Scamehorn, Somchai Osuwan
Abstract
WAROPHAT KIMCHUWANIT, John F. Scamehorn, Somchai Osuwan
Abstract
At temperatures above the cloud point, aqueous nonionic surfactant solutions can separate into two phases: a surfactant-rich coacervate phase and a surfactant-dilute phase. Since the coacervate phase can be a concentrated micellar solution, organic solute tends to concentrate in the coacervate due to solubilization. In this study, up to 90% of trichloroethylene was shown to be extracted into the coacervate phase in one stage. Increasing temperature, surfactant concentration, and added NaCl concentration all improved the fraction of TCE extracted.
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At temperatures above the cloud point, aqueous nonionic surfactant solutions can separate into two phases: a surfactant-rich coacervate phase and a surfactant-dilute phase. Since the coacervate phase can be a concentrated micellar solution, organic solute tends to concentrate in the coacervate due to solubilization. In this study, up to 90% of trichloroethylene was shown to be extracted into the coacervate phase in one stage. Increasing temperature, surfactant concentration, and added NaCl concentration all improved the fraction of TCE extracted.
Key concepts: Coacervate, Pulmonary surfactant, Cloud point, Chemistry, Phase (matter), Aqueous solution, Chromatography, Trichloroethylene