ChemInform Abstract: Novel Ligand Transformations in Cluster Complexes. α‐CH Bond Activation in a Secondary Carbene Ligand in a Triosmium Cluster.
Richard D. Adams, James E. Babin, Hyun Su Kim
Abstract
Richard D. Adams, James E. Babin, Hyun Su Kim
Abstract
Abstract The carbene cluster (II) synthesized as shown undergoes a photodecarbonylation to form the μ‐carbyne cluster (III) by an α‐CH bond activation in the carbene ligand of (II).
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Abstract The carbene cluster (II) synthesized as shown undergoes a photodecarbonylation to form the μ‐carbyne cluster (III) by an α‐CH bond activation in the carbene ligand of (II).
Key concepts: Carbene, Chemistry, Carbyne, Ligand (biochemistry), Cluster (spacecraft), Stereochemistry, Organic chemistry, Catalysis