2008•Dalian Institute of Chemical Physics, CAS Institutional RepositoryRequires access

Low-temperature catalytic combustion of methane over noble metal catalyst

Sheng Wang, Diannan Gao, Chunxi Zhang, Zhongshan Yuan, Peng Zhang, Wang Shudong

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Abstract

Though higher activity contributes to efficient conversion of methane for noble metal catalysts, poor thermal stability restrains their applications in the removal of VOC and ventilation air methane. So many researches focus on the improvement of their stability. The influences of active components, carriers, additives and precursors on catalytic behaviors over methane combustion catalysts, particularly, Pd catalysts, are examined. Inhibition and promotion of reactive species on methane combustion reaction are analyzed on the basis of the kinetic parameters induced. In conclusion I the deactivation mechanisms are indicated for Pd catalysts, and the reasons resulted in great discrepancy on the results studied are pointed out. Solution to higher availability and reproducibility of research results is proposed.

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What this paper is about

Though higher activity contributes to efficient conversion of methane for noble metal catalysts, poor thermal stability restrains their applications in the removal of VOC and ventilation air methane. So many researches focus on the improvement of their stability. The influences of active components, carriers, additives and precursors on catalytic behaviors over methane combustion catalysts, particularly, Pd catalysts, are examined. Inhibition and promotion of reactive species on methane combustion reaction are analyzed on the basis of the kinetic parameters induced. In conclusion I the deactivation mechanisms are indicated for Pd catalysts, and the reasons resulted in great discrepancy on the results studied are pointed out. Solution to higher availability and reproducibility of research results is proposed.

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OpenAlex reports 4 citations for this work. Citation counts describe recorded attention and do not establish research quality.

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Available abstract

Though higher activity contributes to efficient conversion of methane for noble metal catalysts, poor thermal stability restrains their applications in the removal of VOC and ventilation air methane. So many researches focus on the improvement of their stability. The influences of active components, carriers, additives and precursors on catalytic behaviors over methane combustion catalysts, particularly, Pd catalysts, are examined. Inhibition and promotion of reactive species on methane combustion reaction are analyzed on the basis of the kinetic parameters induced. In conclusion I the deactivation mechanisms are indicated for Pd catalysts, and the reasons resulted in great discrepancy on the results studied are pointed out. Solution to higher availability and reproducibility of research results is proposed.

Key concepts: Catalysis, Methane, Catalytic combustion, Noble metal, Combustion, Chemistry, Inorganic chemistry, Chemical engineering

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