ChemInform Abstract: Nitration of 2,6‐, 2,7‐ and 1,5‐(Carboxymethyloxy/Carboxymethylmercapto)naphthalenes.
V. N. Lisitsyn, Aristidis Tsatsakis
Abstract
V. N. Lisitsyn, Aristidis Tsatsakis
Abstract
Abstract Quantum mechanical calculations on the 2,6‐disubstituted naphthalene (I) reveal that nitration should proceed at position 1 or 5. In fact, nitration of (I) with an equimolar quantity of HNO3 (II) affords the 5‐nitro derivative (III) accompanied by a small amount of the 1‐nitro derivative (IV).
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Abstract Quantum mechanical calculations on the 2,6‐disubstituted naphthalene (I) reveal that nitration should proceed at position 1 or 5. In fact, nitration of (I) with an equimolar quantity of HNO3 (II) affords the 5‐nitro derivative (III) accompanied by a small amount of the 1‐nitro derivative (IV).
Key concepts: Nitration, Chemistry, Naphthalene, Nitro, Derivative (finance), Medicinal chemistry, Organic chemistry, Financial economics