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COMPARISON OF EXTRACTION OF U(VI) FROM NITRIC ACID BY DISULFOXIDES AND TBP

Luo Xiao

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Abstract

Six kinds of disulfoxides (RSO(CH 2) n SOR( n =4,6; R=CH 3(CH 2) 2CH 2 -,CH 3CH(CH 3)CH 2CH 2 -,CH 3 (CH 2) 3CH(C 2H 5)CH 2 -) are synthesized. The extraction of uranium(Ⅵ) from nitric acid solution by disulfoxides is studied and compared with that by TBP. The experimental results show that their extracting ability is superior to that by TBP.

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What this paper is about

Six kinds of disulfoxides (RSO(CH 2) n SOR( n =4,6; R=CH 3(CH 2) 2CH 2 -,CH 3CH(CH 3)CH 2CH 2 -,CH 3 (CH 2) 3CH(C 2H 5)CH 2 -) are synthesized. The extraction of uranium(Ⅵ) from nitric acid solution by disulfoxides is studied and compared with that by TBP. The experimental results show that their extracting ability is superior to that by TBP.

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Available abstract

Six kinds of disulfoxides (RSO(CH 2) n SOR( n =4,6; R=CH 3(CH 2) 2CH 2 -,CH 3CH(CH 3)CH 2CH 2 -,CH 3 (CH 2) 3CH(C 2H 5)CH 2 -) are synthesized. The extraction of uranium(Ⅵ) from nitric acid solution by disulfoxides is studied and compared with that by TBP. The experimental results show that their extracting ability is superior to that by TBP.

Key concepts: Chemistry, Nitric acid, Extraction (chemistry), Uranium, Nuclear chemistry, Medicinal chemistry, Inorganic chemistry, Chromatography

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