2001Nuclear TechniquesRequires access

Comparision of extraction of U(VI) from nitric acid by disulfoxides and TBP

Zhu Liming

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Abstract

The extraction of dioxouranium(Ⅵ) from nitric acid solution by PhSO(CH 2) nSOPh ( n =2,3,4,6)-trichloromethane was studied. When the disulfoxide was PhSO(CH 2) 2SOPh, the third phase formed. The extraction laws of dioxouranium(Ⅵ) by the disulfoxides ( n =3,4,6) were similar to that by tributyl-phosphate(TBP). Their extracting ability was slightly better than that of TBP.

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The extraction of dioxouranium(Ⅵ) from nitric acid solution by PhSO(CH 2) nSOPh ( n =2,3,4,6)-trichloromethane was studied. When the disulfoxide was PhSO(CH 2) 2SOPh, the third phase formed. The extraction laws of dioxouranium(Ⅵ) by the disulfoxides ( n =3,4,6) were similar to that by tributyl-phosphate(TBP). Their extracting ability was slightly better than that of TBP.

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Available abstract

The extraction of dioxouranium(Ⅵ) from nitric acid solution by PhSO(CH 2) nSOPh ( n =2,3,4,6)-trichloromethane was studied. When the disulfoxide was PhSO(CH 2) 2SOPh, the third phase formed. The extraction laws of dioxouranium(Ⅵ) by the disulfoxides ( n =3,4,6) were similar to that by tributyl-phosphate(TBP). Their extracting ability was slightly better than that of TBP.

Key concepts: Nitric acid, Tributyl phosphate, Extraction (chemistry), Chemistry, Nuclear chemistry, Third phase, Phosphate, Phase (matter)

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