Synthesis and Crystal Structure of Schiff Base Pd(II) Complex

Pd(II) complex of Schiff base(C_(7)H_(7)NO) was synthesized and its crystal structure was determined by X-ray diffraction technique.The crystal belongs to uriclinic system,Pī space group.The crystallographic data are: a=0.945 8(19) nm,b=1.059 9(2) nm,c=1.396 5(3) nm,α=74.61(3)°,β=75.18(3)°,γ=68.49(3)°,V=1.236(4) nm~(3),D_(c)=1.594 Mg/m~(3),M_(r)=1 186.16,Z=1,F(000)=596,R_(1)=0.029 9,wR_(2)=0.073 4.The crystal structure data indicated that the Pd(Ⅱ) ion was coordinated through two oxygen and two nitrogen atoms from two free ligands,yielding two six-membered chelate rings.