2007•Unpublished venueRequires access

Hydrothermal synthesis and characterization of a novel heteropoly blue compound [NH_3(CH_2)_2NH_3]_5[Cd(H_2O)][CdMo_(12)~VO_(30)(HPO_4)_6(H_2PO_4)_2]·5H_2O

Xueqin Xu

Abstract

A novel heteropoly blue compound containing Cd atoms with two coordination environment,[NH3(CH2)2NH3]5[Cd(H2O)][CdMoⅤ12O30(HPO4)6(H2PO4)2]·5H2O was first prepared by hydrothermal synthesis and confirmed composition by elemental analysis,ICP,TG and single crystal X-ray diffraction.The title compound was characterized by IR and EPR.The catalytical properties of title compound was investigated by N2 adsorption/desorption.Crystal data:Triclinic,space group P-1,a=1.200 2(2) nm,b=1.465 1(3) nm,c=2.119 2(4) nm,V=3.564 2(12) nm3,β=83.01(3)°,Z=2,F(000)=2 932,R1=0.030 0,wR2=0.071 6.

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Key concepts: Triclinic crystal system, Hydrothermal synthesis, Hydrothermal circulation, Chemistry, Crystallography, Electron paramagnetic resonance, Single crystal, Polyoxometalate