2006•Hebei Chemical Engineering and IndustryRequires access

Progress of Atom Transfer Radical Polymerization

Desong Wang

Abstract

Atom transfer radical polymerization (ATRP), which can yield polymers with controlled molecular weight and low polydispersity, is an effective approach to realize living radical polymerization. This article introduces the progress of ATRP, including reactive characteristics? polymerization mechanism? application?up-to-date investigation situation and the prospect.

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Key concepts: Atom-transfer radical-polymerization, Dispersity, Living free-radical polymerization, Polymerization, Reversible addition−fragmentation chain-transfer polymerization, Radical polymerization, Cobalt-mediated radical polymerization, Living polymerization