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Recent Advances on Atom Transfer Radical Polymerization

LU Qing-wen

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Abstract

Atom transfer radical polymerization(ATRP),which can yield polymers with controlled molecular weight and low polydispersity,is an effective approach to realize living radical polymerization.In this article,the up-to-date investigation progresses of ATRP,including the development of initiator,catalytic system, polymerization mechanism are introduced,and the application prospect of ATRP is also viewed.

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What this paper is about

Atom transfer radical polymerization(ATRP),which can yield polymers with controlled molecular weight and low polydispersity,is an effective approach to realize living radical polymerization.In this article,the up-to-date investigation progresses of ATRP,including the development of initiator,catalytic system, polymerization mechanism are introduced,and the application prospect of ATRP is also viewed.

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Available abstract

Atom transfer radical polymerization(ATRP),which can yield polymers with controlled molecular weight and low polydispersity,is an effective approach to realize living radical polymerization.In this article,the up-to-date investigation progresses of ATRP,including the development of initiator,catalytic system, polymerization mechanism are introduced,and the application prospect of ATRP is also viewed.

Key concepts: Atom-transfer radical-polymerization, Living free-radical polymerization, Dispersity, Reversible addition−fragmentation chain-transfer polymerization, Polymerization, Radical polymerization, Cobalt-mediated radical polymerization, Living polymerization

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