Studies on catalytic kinetic spectrophotometric determination of trace nitrite
Fang Yan
Abstract
Fang Yan
Abstract
Based on the catalytic effect of trace nitrite on the oxidation of chlorophenol red with potassium bromate in the medium of H 3PO 4,a determination of nitrite was established by catalytic kinetic spectrophotometry.The linear range of the determination for nitrite is 0 04~14?mg/L with the detection limit of 0 007?mg/L,and the recoveries are between 98 7%~102%.This method is simple,fast,with good selectivity,and has been applied to the determination of trace nitrite in water,foods and soil samples with satisfactory results.
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Based on the catalytic effect of trace nitrite on the oxidation of chlorophenol red with potassium bromate in the medium of H 3PO 4,a determination of nitrite was established by catalytic kinetic spectrophotometry.The linear range of the determination for nitrite is 0 04~14?mg/L with the detection limit of 0 007?mg/L,and the recoveries are between 98 7%~102%.This method is simple,fast,with good selectivity,and has been applied to the determination of trace nitrite in water,foods and soil samples with satisfactory results.
Key concepts: Potassium bromate, Nitrite, Chemistry, Detection limit, Spectrophotometry, Catalysis, Linear range, Bromate