2013•Journal of Central South University(Science and Technology)Requires access

Adsorption properties of modified activated carbon for 2-dichloroethane

Xiaolong Yao

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Abstract

To study the adsorption characteristics of organic vapor on modified activated carbon,commercial activated carbon was treated separately with 1 mol/L nitric acid,1 mol/L sulfuric acid,1 mol/L hydrochloric acid at 600,700 and 800 ℃.Physicochemical properties of these modified activated carbons were described by Boehm titration;Fourier transformed infrared spectroscopy(FTIR) and BET surface area measurement.The adsorption experiments were conducted with 2-dichloroethane acting as adsorbate.The results show that the total amount of acid groups increase after acid modification,while the amount of basic groups increases after heating modification;heating modification is more effective than acid modification for optimizing pore structure of activated carbon;increasing the effective pore volume is an effective way to improve adsorption capacity of 2-dichloroethane,while raising the surface functional groups can stimulate absorption effect of 2-dichloroethane.

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What this paper is about

To study the adsorption characteristics of organic vapor on modified activated carbon,commercial activated carbon was treated separately with 1 mol/L nitric acid,1 mol/L sulfuric acid,1 mol/L hydrochloric acid at 600,700 and 800 ℃.Physicochemical properties of these modified activated carbons were described by Boehm titration;Fourier transformed infrared spectroscopy(FTIR) and BET surface area measurement.The adsorption experiments were conducted with 2-dichloroethane acting as adsorbate.The results show that the total amount of acid groups increase after acid modification,while the amount of basic groups increases after heating modification;heating modification is more effective than acid modification for optimizing pore structure of activated carbon;increasing the effective pore volume is an effective way to improve adsorption capacity of 2-dichloroethane,while raising the surface functional groups can stimulate absorption effect of 2-dichloroethane.

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Available abstract

To study the adsorption characteristics of organic vapor on modified activated carbon,commercial activated carbon was treated separately with 1 mol/L nitric acid,1 mol/L sulfuric acid,1 mol/L hydrochloric acid at 600,700 and 800 ℃.Physicochemical properties of these modified activated carbons were described by Boehm titration;Fourier transformed infrared spectroscopy(FTIR) and BET surface area measurement.The adsorption experiments were conducted with 2-dichloroethane acting as adsorbate.The results show that the total amount of acid groups increase after acid modification,while the amount of basic groups increases after heating modification;heating modification is more effective than acid modification for optimizing pore structure of activated carbon;increasing the effective pore volume is an effective way to improve adsorption capacity of 2-dichloroethane,while raising the surface functional groups can stimulate absorption effect of 2-dichloroethane.

Key concepts: Activated carbon, Adsorption, Sulfuric acid, Nitric acid, 1,2-Dichloroethane, Chemistry, Titration, Dichloroethane

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