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Research Progress in Initiation Systems of Atom Transfer "Living"/Controlled Radical Polymerization

Wang Cun-dong

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Abstract

Atom transfer radical polymerization(ATRP) was an effective approach to realize living radical polymerization,which could synthesize various shape polymers with controlled molecular weight and low polydispersity.The research progress of living/controlled ATRP,included RATRP,SRNI ATRP,AGET ATRP Pseudo-halogen transfer ATRP and ATRP with novel catalyst systems,etc,were introduced,and the polymerization mechanism about them was explained.

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What this paper is about

Atom transfer radical polymerization(ATRP) was an effective approach to realize living radical polymerization,which could synthesize various shape polymers with controlled molecular weight and low polydispersity.The research progress of living/controlled ATRP,included RATRP,SRNI ATRP,AGET ATRP Pseudo-halogen transfer ATRP and ATRP with novel catalyst systems,etc,were introduced,and the polymerization mechanism about them was explained.

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Available abstract

Atom transfer radical polymerization(ATRP) was an effective approach to realize living radical polymerization,which could synthesize various shape polymers with controlled molecular weight and low polydispersity.The research progress of living/controlled ATRP,included RATRP,SRNI ATRP,AGET ATRP Pseudo-halogen transfer ATRP and ATRP with novel catalyst systems,etc,were introduced,and the polymerization mechanism about them was explained.

Key concepts: Atom-transfer radical-polymerization, Living free-radical polymerization, Reversible addition−fragmentation chain-transfer polymerization, Dispersity, Polymerization, Radical polymerization, Living polymerization, Cobalt-mediated radical polymerization

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