2004•Unpublished venueRequires access

Catalytic synthesis of ethyl acetoacetate 1,2-Propanediol ketal with H_3PW_(12)O_(40)/PAn

Yang Shui-jin

Abstract

Ethyl acetoacetate 1,2-propanediol ketal was synthesized from ethyl acetoacetate and 1,2-propylene glycol in the presence of H_3PW_(12)O_(40)/PAn.The factors influencing the synthesis were discussed and the optimum conditions were found out.The optimum conditions are:molar ratio of ethyl acetoacetate to 1,2-propylene glycol was 1∶1.5,the quantity of catalyst was equal to 1.0% of feed stocks,and the reaction time was 50 min.H_3PW_(12)O_(40)/PAn was an excellent catalyst for synthesizing ethyl acetoacetate 1,2-propanediol ketal and its yield can reach over 85.0%.

About this research paper

What this paper is about

Why it matters

A significance statement is not available in the OpenAlex record.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

Key concepts: Ethyl acetoacetate, Propanediol, Catalysis, Yield (engineering), Chemistry, Molar ratio, 1,3-Propanediol, Organic chemistry