2002Journal of Inner Mongolia Polytechnic UniversityRequires access

A STUDY OF THE SYNTHESIS OF CYCLOHEXYL ACETATE CATALYZED BY SO_4~(2-)/TiO_2/Y~(3+) RARE-EARTH SOLID SUPERACID

Yaquan Wang

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Abstract

Cyclohexyl acetate has been synthesized from acetic acid and cyclohexanol,catalyzed by SO2-4/TiO2/Y3+ rareearth solid superacid.Various factors affecting the reaction have been studied.Results show that the rareearth solid superacid SO2-4/TiO2/Y3+ is an excellent catalyst for the synthesis of cyclohexyl acetate.Optimum conditions for the reaction are:the mass ratio of the catalyst to the reactants-2.3%,the molar ratio of alcohol to acid-1∶2,the reaction time60 min,and the mass ratio of the waterborne reagent to the reactants-12%.Under such conditions,the yield of cyclohexyl acetate amounts to 85%.

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Cyclohexyl acetate has been synthesized from acetic acid and cyclohexanol,catalyzed by SO2-4/TiO2/Y3+ rareearth solid superacid.Various factors affecting the reaction have been studied.Results show that the rareearth solid superacid SO2-4/TiO2/Y3+ is an excellent catalyst for the synthesis of cyclohexyl acetate.Optimum conditions for the reaction are:the mass ratio of the catalyst to the reactants-2.3%,the molar ratio of alcohol to acid-1∶2,the reaction time60 min,and the mass ratio of the waterborne reagent to the reactants-12%.Under such conditions,the yield of cyclohexyl acetate amounts to 85%.

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Available abstract

Cyclohexyl acetate has been synthesized from acetic acid and cyclohexanol,catalyzed by SO2-4/TiO2/Y3+ rareearth solid superacid.Various factors affecting the reaction have been studied.Results show that the rareearth solid superacid SO2-4/TiO2/Y3+ is an excellent catalyst for the synthesis of cyclohexyl acetate.Optimum conditions for the reaction are:the mass ratio of the catalyst to the reactants-2.3%,the molar ratio of alcohol to acid-1∶2,the reaction time60 min,and the mass ratio of the waterborne reagent to the reactants-12%.Under such conditions,the yield of cyclohexyl acetate amounts to 85%.

Key concepts: Superacid, Catalysis, Cyclohexanol, Acetic acid, Yield (engineering), Reagent, Chemistry, Molar ratio

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A STUDY OF THE SYNTHESIS OF CYCLOHEXYL ACETATE CATALYZED BY SO_4~(2-)/TiO_2/Y~(3+) RARE-EARTH SOLID SUPERACID — Research Paper | ScholarLens