ScholarLens Back to search
2005•Journal of Natural Science of Heilongjiang UniversityRequires access

Synhesis, crystal structure of complex[Ni(m-CPOAH)_2·(H_2O)_4] with 3-carboxyphenoxyacetate ligand

Chang-Sheng Gu

Open publisher page 0 citations

Abstract

A novel complex of [Ni(m-CPOAH)_2·(H_2O)_4](m-CPOAH~(-)=3-carboxylphenoxyacetate) was synthesized and characterized by elemental analysis, IR, X-ray single crystal diffraction. The title complex belongs to triclinic system with space group P, a=0.49412(10)nm, b=0.57963(12)nm, c=1.8362(4)nm,α=96.94(3)°,β=94.82(3)°,γ=97.91(3)°. V=0.51436(18)nm~3, Z=1, M_r=521.07, D_c=1.682g·cm~(-3), μ=1.020mm~(-1), F(000)=270, R=0.0337, wR=0.0822. Two oxoacetate oxygen atoms of different m-CPOAH~(-) ligands and four water molecules are coordinated to nickel atom. The nickel atom displays an octahedral coordination sphere. The supramolecular hydrogen bonding network structure is formed by the intermolecular hydrogen bonds.

About this research paper

What this paper is about

A novel complex of [Ni(m-CPOAH)_2·(H_2O)_4](m-CPOAH~(-)=3-carboxylphenoxyacetate) was synthesized and characterized by elemental analysis, IR, X-ray single crystal diffraction. The title complex belongs to triclinic system with space group P, a=0.49412(10)nm, b=0.57963(12)nm, c=1.8362(4)nm,α=96.94(3)°,β=94.82(3)°,γ=97.91(3)°. V=0.51436(18)nm~3, Z=1, M_r=521.07, D_c=1.682g·cm~(-3), μ=1.020mm~(-1), F(000)=270, R=0.0337, wR=0.0822. Two oxoacetate oxygen atoms of different m-CPOAH~(-) ligands and four water molecules are coordinated to nickel atom. The nickel atom displays an octahedral coordination sphere. The supramolecular hydrogen bonding network structure is formed by the intermolecular hydrogen bonds.

Why it matters

A significance statement is not available in the OpenAlex record.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

A novel complex of [Ni(m-CPOAH)_2·(H_2O)_4](m-CPOAH~(-)=3-carboxylphenoxyacetate) was synthesized and characterized by elemental analysis, IR, X-ray single crystal diffraction. The title complex belongs to triclinic system with space group P, a=0.49412(10)nm, b=0.57963(12)nm, c=1.8362(4)nm,α=96.94(3)°,β=94.82(3)°,γ=97.91(3)°. V=0.51436(18)nm~3, Z=1, M_r=521.07, D_c=1.682g·cm~(-3), μ=1.020mm~(-1), F(000)=270, R=0.0337, wR=0.0822. Two oxoacetate oxygen atoms of different m-CPOAH~(-) ligands and four water molecules are coordinated to nickel atom. The nickel atom displays an octahedral coordination sphere. The supramolecular hydrogen bonding network structure is formed by the intermolecular hydrogen bonds.

Key concepts: Triclinic crystal system, Crystallography, Nickel, Crystal structure, Hydrogen bond, Molecule, Ligand (biochemistry), Octahedron

Related papers

Related paper 1Related paper 2Related paper 3
Back to paper searchBrowse research topicsOriginal source
Synhesis, crystal structure of complex[Ni(m-CPOAH)_2·(H_2O)_4] with 3-carboxyphenoxyacetate ligand — Research Paper | ScholarLens