2012Huagong jinzhanRequires access

Comparision of performances of iron and cobalt in Fischer-Tropsch synthesis

Jianfang Cao

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Abstract

This paper examines the Fischer-Tropsch technology for the biomass-to-clean fuels scenario.A comparison of the activities,selectivities and lifetimes of iron and cobalt catalysts for Fischer-Tropsch synthesis is made.For the more severe conditions,iron is the more active catalyst,whereas a cobalt catalyst may be more active at low severity conditions.In spite of many reports,there are still considerable differences in defining catalyst activity.The selectivity for methane likewise shows a wide range of reported results.Under the proper conditions,both catalysts are capable of operating for 6 months or more.

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This paper examines the Fischer-Tropsch technology for the biomass-to-clean fuels scenario.A comparison of the activities,selectivities and lifetimes of iron and cobalt catalysts for Fischer-Tropsch synthesis is made.For the more severe conditions,iron is the more active catalyst,whereas a cobalt catalyst may be more active at low severity conditions.In spite of many reports,there are still considerable differences in defining catalyst activity.The selectivity for methane likewise shows a wide range of reported results.Under the proper conditions,both catalysts are capable of operating for 6 months or more.

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Available abstract

This paper examines the Fischer-Tropsch technology for the biomass-to-clean fuels scenario.A comparison of the activities,selectivities and lifetimes of iron and cobalt catalysts for Fischer-Tropsch synthesis is made.For the more severe conditions,iron is the more active catalyst,whereas a cobalt catalyst may be more active at low severity conditions.In spite of many reports,there are still considerable differences in defining catalyst activity.The selectivity for methane likewise shows a wide range of reported results.Under the proper conditions,both catalysts are capable of operating for 6 months or more.

Key concepts: Fischer–Tropsch process, Cobalt, Catalysis, Methane, Selectivity, Chemistry, Chemical engineering, Inorganic chemistry

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