2014Journal of Beijing University of TechnologyRequires access

Characteristics and Source Apportionment of Organic Carbon and Elemental Carbon in PM_(2.5) During the Heating Season in Beijing

Cheng Shui-yua

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Abstract

This paper investigated the characteristics and sources of organic carbon(OC) and elemental carbon(EC) in PM2. 5during the heating season in Beijing. PM2. 5samples were collected at the Beijing Normal University sample site during the period of December 2011 to February 2012. This study also analyzed the concentrations characteristics of PM2. 5,OC and EC,calculated the concentrations of the secondary organic carbon(SOC) based on the minimum ρ(OC)/ρ(EC) ratio method. Besides,the sources and source contributions of OC and EC were analyzed qualitatively and quantitatively. Results showed that the average concentration of PM2. 5was(90. 69 ± 61. 86) μg/m3,the average concentration of OC and EC were(21. 91 ± 12. 02),(5. 03 ± 2. 58) μg/m3,accounting for 24. 16% and 5. 55% of PM2. 5,respectively. The average concentration of SOC was(8. 37 ± 6. 05) μg/m3,accounting for37. 27% of the total organic carbon(TOC). The high correlation coefficient of OC and EC showed that the source for OC and EC was the same,mainly from the vehicle emission,the coal combustion. The vehicle emission was the major source,with a contribution of 44. 70% to the OC and EC. As a consequence,controlling the number and reducing the emissions of motor vehicles have become an important measure to improve the atmospheric environment quality in urban areas.

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What this paper is about

This paper investigated the characteristics and sources of organic carbon(OC) and elemental carbon(EC) in PM2. 5during the heating season in Beijing. PM2. 5samples were collected at the Beijing Normal University sample site during the period of December 2011 to February 2012. This study also analyzed the concentrations characteristics of PM2. 5,OC and EC,calculated the concentrations of the secondary organic carbon(SOC) based on the minimum ρ(OC)/ρ(EC) ratio method. Besides,the sources and source contributions of OC and EC were analyzed qualitatively and quantitatively. Results showed that the average concentration of PM2. 5was(90. 69 ± 61. 86) μg/m3,the average concentration of OC and EC were(21. 91 ± 12. 02),(5. 03 ± 2. 58) μg/m3,accounting for 24. 16% and 5. 55% of PM2. 5,respectively. The average concentration of SOC was(8. 37 ± 6. 05) μg/m3,accounting for37. 27% of the total organic carbon(TOC). The high correlation coefficient of OC and EC showed that the source for OC and EC was the same,mainly from the vehicle emission,the coal combustion. The vehicle emission was the major source,with a contribution of 44. 70% to the OC and EC. As a consequence,controlling the number and reducing the emissions of motor vehicles have become an important measure to improve the atmospheric environment quality in urban areas.

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Available abstract

This paper investigated the characteristics and sources of organic carbon(OC) and elemental carbon(EC) in PM2. 5during the heating season in Beijing. PM2. 5samples were collected at the Beijing Normal University sample site during the period of December 2011 to February 2012. This study also analyzed the concentrations characteristics of PM2. 5,OC and EC,calculated the concentrations of the secondary organic carbon(SOC) based on the minimum ρ(OC)/ρ(EC) ratio method. Besides,the sources and source contributions of OC and EC were analyzed qualitatively and quantitatively. Results showed that the average concentration of PM2. 5was(90. 69 ± 61. 86) μg/m3,the average concentration of OC and EC were(21. 91 ± 12. 02),(5. 03 ± 2. 58) μg/m3,accounting for 24. 16% and 5. 55% of PM2. 5,respectively. The average concentration of SOC was(8. 37 ± 6. 05) μg/m3,accounting for37. 27% of the total organic carbon(TOC). The high correlation coefficient of OC and EC showed that the source for OC and EC was the same,mainly from the vehicle emission,the coal combustion. The vehicle emission was the major source,with a contribution of 44. 70% to the OC and EC. As a consequence,controlling the number and reducing the emissions of motor vehicles have become an important measure to improve the atmospheric environment quality in urban areas.

Key concepts: Total organic carbon, Beijing, Environmental chemistry, Carbon fibers, Coal combustion products, Environmental science, Correlation coefficient, Combustion

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