2006•Journal of Chengdu University of Information TechnologyRequires access

Rapid determination of COD in water sample by using potassium dichromate

L Zhang

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Abstract

A new analytical method of the chemical oxygen demand(COD) for water sample is developed.The manganese sulfate substitutes the silver sulfate for the catalyst with the H_2SO_4-H_3PO_4 instead of H_2SO_4.The results show that the optimal condition is the 1x10~(-1) mol.L~(-1) of manganese sulfate with the ratio of H_2SO_4 to H_3PO_4=5:1 and 10-minutes of the condensation time.It is compared with the standard model and the analytical time is greatly reduced with almost the same accuracy and precision.

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What this paper is about

A new analytical method of the chemical oxygen demand(COD) for water sample is developed.The manganese sulfate substitutes the silver sulfate for the catalyst with the H_2SO_4-H_3PO_4 instead of H_2SO_4.The results show that the optimal condition is the 1x10~(-1) mol.L~(-1) of manganese sulfate with the ratio of H_2SO_4 to H_3PO_4=5:1 and 10-minutes of the condensation time.It is compared with the standard model and the analytical time is greatly reduced with almost the same accuracy and precision.

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Available abstract

A new analytical method of the chemical oxygen demand(COD) for water sample is developed.The manganese sulfate substitutes the silver sulfate for the catalyst with the H_2SO_4-H_3PO_4 instead of H_2SO_4.The results show that the optimal condition is the 1x10~(-1) mol.L~(-1) of manganese sulfate with the ratio of H_2SO_4 to H_3PO_4=5:1 and 10-minutes of the condensation time.It is compared with the standard model and the analytical time is greatly reduced with almost the same accuracy and precision.

Key concepts: Potassium dichromate, Manganese, Sulfate, Potassium, Chemical oxygen demand, Potassium sulfate, Condensation, Chemistry

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