2006•Chemical Research and ApplicationRequires access

Synthesis and catalytic properties of transition metal complexes with unsymmetrical schiff base

Fengqin Gao

Abstract

An unsymmetrical tetradentate Schiff base ligand(H_2L)and its copper(Ⅱ),cobalt(Ⅱ),nickel(Ⅱ)and zinc(Ⅱ)complexes have been synthesized from the reaction of ethylenediamine,acetylacetone and salicylaldehyde and characterized by elemental analysis,molar conductance,IR,UV-VIS and XPS.A four-coordinated enol model is proposed for these complexes.The compostion of newcoordination compounds is MC_(14)H_(16)N_2O_2(M=Cu,Co,Ni,Zn).The catalysis of these complexes to decomposition of hydrogen peroxide has also been studied.

About this research paper

What this paper is about

Why it matters

OpenAlex reports 1 citations for this work. Citation counts describe recorded attention and do not establish research quality.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

Key concepts: Schiff base, Acetylacetone, Salicylaldehyde, Chemistry, Catalysis, Cobalt, Ethylenediamine, Transition metal