ScholarLens Back to search
2008•Journal of Hebei UniversityRequires access

Oxidation of Cyclohexanol with Tungsten-based Catalysts

Hui-Sen Ning

Open publisher page 0 citations

Abstract

The selective oxidation of cyclohexanol to cyclohexanone was studied systematically using WO3,Na2WO4·2H2O,Na9[SbW9O33] and the prepared 9[SbW9O33] as tungsten-based catalysts and H2O2 as oxidant. The influence of the amount of substance ratio of the starting materials,the temperature and the reaction time were improved.9[SbW9O33] showed the highest catalytic activity.The conversion of cyclohexanol reaches 97.4% and the selectivity to cyclohexanone is 99.7% within 2 hours,while the temperature is 80 ℃ and the ratio of n(H2O2)∶n(cyclohexanol)∶n(9[SbW9O33]) is 75∶50∶0.06.

About this research paper

What this paper is about

The selective oxidation of cyclohexanol to cyclohexanone was studied systematically using WO3,Na2WO4·2H2O,Na9[SbW9O33] and the prepared 9[SbW9O33] as tungsten-based catalysts and H2O2 as oxidant. The influence of the amount of substance ratio of the starting materials,the temperature and the reaction time were improved.9[SbW9O33] showed the highest catalytic activity.The conversion of cyclohexanol reaches 97.4% and the selectivity to cyclohexanone is 99.7% within 2 hours,while the temperature is 80 ℃ and the ratio of n(H2O2)∶n(cyclohexanol)∶n(9[SbW9O33]) is 75∶50∶0.06.

Why it matters

A significance statement is not available in the OpenAlex record.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

The selective oxidation of cyclohexanol to cyclohexanone was studied systematically using WO3,Na2WO4·2H2O,Na9[SbW9O33] and the prepared 9[SbW9O33] as tungsten-based catalysts and H2O2 as oxidant. The influence of the amount of substance ratio of the starting materials,the temperature and the reaction time were improved.9[SbW9O33] showed the highest catalytic activity.The conversion of cyclohexanol reaches 97.4% and the selectivity to cyclohexanone is 99.7% within 2 hours,while the temperature is 80 ℃ and the ratio of n(H2O2)∶n(cyclohexanol)∶n(9[SbW9O33]) is 75∶50∶0.06.

Key concepts: Cyclohexanol, Cyclohexanone, Chemistry, Tungsten, Catalysis, Selectivity, Inorganic chemistry, Organic chemistry

Related papers

Related paper 1Related paper 2Related paper 3
Back to paper searchBrowse research topicsOriginal source
Oxidation of Cyclohexanol with Tungsten-based Catalysts — Research Paper | ScholarLens