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Supramolecular polymers and their application as coating materials

Yu Wang

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Abstract

Supramolecular polymers which are formed via non-covalent bonding possess many unique properties.Up to date,three main categories of non-covalent bonding,including coordination,π-stacking and hydrogen bonding,have been used in assembling such polymers.It was found that hyperbranched polymers bearing ureidopyrimidone(Upy) units display good coating performances due to the formation of self-complementary quadruple hydrogen bonding of Upy units.Their melt viscosities are decreased sharply with increasing temperature,which makes the polymers suitable for use as novel hot-melting coating materials.

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Supramolecular polymers which are formed via non-covalent bonding possess many unique properties.Up to date,three main categories of non-covalent bonding,including coordination,π-stacking and hydrogen bonding,have been used in assembling such polymers.It was found that hyperbranched polymers bearing ureidopyrimidone(Upy) units display good coating performances due to the formation of self-complementary quadruple hydrogen bonding of Upy units.Their melt viscosities are decreased sharply with increasing temperature,which makes the polymers suitable for use as novel hot-melting coating materials.

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Available abstract

Supramolecular polymers which are formed via non-covalent bonding possess many unique properties.Up to date,three main categories of non-covalent bonding,including coordination,π-stacking and hydrogen bonding,have been used in assembling such polymers.It was found that hyperbranched polymers bearing ureidopyrimidone(Upy) units display good coating performances due to the formation of self-complementary quadruple hydrogen bonding of Upy units.Their melt viscosities are decreased sharply with increasing temperature,which makes the polymers suitable for use as novel hot-melting coating materials.

Key concepts: Polymer, Hydrogen bond, Stacking, Materials science, Coating, Supramolecular chemistry, Covalent bond, Supramolecular polymers

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