2013•Huagong jinzhanRequires access

Tungsten ionic liquids: Application of cyclohexanol oxidation

Shuliang Zang

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Abstract

The ionic liquid [(CH3)N(n-C8H17)3]2W2O11 can be applied as a catalyst in cyclohexanol oxidation.Experiments show that it has good catalytic activity on cyclohexanol oxidation with H2O2 as the oxidant.It was conducted at 65 ℃ by adding substrate(5 mmol),catalyst(50 μmol) and H2O2(15 mmol) in a stirred mixture in a reactor.The yield is more than 99 %.The catalyst could be recycled after simple filtering.

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What this paper is about

The ionic liquid [(CH3)N(n-C8H17)3]2W2O11 can be applied as a catalyst in cyclohexanol oxidation.Experiments show that it has good catalytic activity on cyclohexanol oxidation with H2O2 as the oxidant.It was conducted at 65 ℃ by adding substrate(5 mmol),catalyst(50 μmol) and H2O2(15 mmol) in a stirred mixture in a reactor.The yield is more than 99 %.The catalyst could be recycled after simple filtering.

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Available abstract

The ionic liquid [(CH3)N(n-C8H17)3]2W2O11 can be applied as a catalyst in cyclohexanol oxidation.Experiments show that it has good catalytic activity on cyclohexanol oxidation with H2O2 as the oxidant.It was conducted at 65 ℃ by adding substrate(5 mmol),catalyst(50 μmol) and H2O2(15 mmol) in a stirred mixture in a reactor.The yield is more than 99 %.The catalyst could be recycled after simple filtering.

Key concepts: Cyclohexanol, Ionic liquid, Catalysis, Tungsten, Yield (engineering), Chemistry, Substrate (aquarium), Inorganic chemistry

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