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Simultaneous Determination of Co~(2+) and Ni~(2+) Content in Alloy Electrolyte by Spectrophotometric Method

Chen Hai-chun

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Abstract

A method is reported for the simultaneous determination of cobalt and nickel content in alloy electrolyte by dual-wavelength K coefficient spectrophotometry.In this method,PAR is used as chromogenic reagent and the measurement is conducted in NH3-H2O-NH4Cl buffer solution of pH=8.0.The reference wavelength of cobalt and nickel are 512 nm/482 nm and 496 nm/526 nm,respectively.At these wavelengths,the linear ranges are 0.080~1.0 μg/mL for cobalt and 0.040~1.0 μg/mL for nickel.This method has been applied successfully to the analysis of cobalt and nickel in alloy electrolyte.

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What this paper is about

A method is reported for the simultaneous determination of cobalt and nickel content in alloy electrolyte by dual-wavelength K coefficient spectrophotometry.In this method,PAR is used as chromogenic reagent and the measurement is conducted in NH3-H2O-NH4Cl buffer solution of pH=8.0.The reference wavelength of cobalt and nickel are 512 nm/482 nm and 496 nm/526 nm,respectively.At these wavelengths,the linear ranges are 0.080~1.0 μg/mL for cobalt and 0.040~1.0 μg/mL for nickel.This method has been applied successfully to the analysis of cobalt and nickel in alloy electrolyte.

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Available abstract

A method is reported for the simultaneous determination of cobalt and nickel content in alloy electrolyte by dual-wavelength K coefficient spectrophotometry.In this method,PAR is used as chromogenic reagent and the measurement is conducted in NH3-H2O-NH4Cl buffer solution of pH=8.0.The reference wavelength of cobalt and nickel are 512 nm/482 nm and 496 nm/526 nm,respectively.At these wavelengths,the linear ranges are 0.080~1.0 μg/mL for cobalt and 0.040~1.0 μg/mL for nickel.This method has been applied successfully to the analysis of cobalt and nickel in alloy electrolyte.

Key concepts: Cobalt, Chromogenic, Nickel, Electrolyte, Reagent, Alloy, Spectrophotometry, Materials science

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