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2006•Journal of Fujian Normal UniversityRequires access

Synthesis,Crystal Structure and Property of Three-dimensional Supramolecular Complex[Zn(C_(13)H_(14)N_2)(C_8H_4O_4)]_n·0.5nH_2O

Hui-Ying Shen

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Abstract

The reaction of Zn salts with BPP(BPP=1,3-bis(4-pyridyl)propane) and H_2ip(ip=isophthalate) gave rise to diamondoid topological architecture,namely,[Zn(C_(13)H_(14)N_2)(C_8H_4O_4)]_n·0.5nH_2O.The complexes have been fully characterized by infrared spectroscopy,elemental analysis,single-crystal X-ray diffraction analysis,fluorescent spectrum and TGA.The crystal structure is of monoclinic,space group P2(1)/n,a=1.104 18(13)nm,b=1.119 24(14)nm,c=1.573 45(18)nm,α=90(°),β=104.150(5)(°),γ=90(°),Mr=436.75,V=1.885 5(4) nm~3,Z=4,Dc=(1.539 mg·m~(-3)),F(000)=900,GOF=1.073,R_1=0.038 1,ωR_2=0.100 2.

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The reaction of Zn salts with BPP(BPP=1,3-bis(4-pyridyl)propane) and H_2ip(ip=isophthalate) gave rise to diamondoid topological architecture,namely,[Zn(C_(13)H_(14)N_2)(C_8H_4O_4)]_n·0.5nH_2O.The complexes have been fully characterized by infrared spectroscopy,elemental analysis,single-crystal X-ray diffraction analysis,fluorescent spectrum and TGA.The crystal structure is of monoclinic,space group P2(1)/n,a=1.104 18(13)nm,b=1.119 24(14)nm,c=1.573 45(18)nm,α=90(°),β=104.150(5)(°),γ=90(°),Mr=436.75,V=1.885 5(4) nm~3,Z=4,Dc=(1.539 mg·m~(-3)),F(000)=900,GOF=1.073,R_1=0.038 1,ωR_2=0.100 2.

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Available abstract

The reaction of Zn salts with BPP(BPP=1,3-bis(4-pyridyl)propane) and H_2ip(ip=isophthalate) gave rise to diamondoid topological architecture,namely,[Zn(C_(13)H_(14)N_2)(C_8H_4O_4)]_n·0.5nH_2O.The complexes have been fully characterized by infrared spectroscopy,elemental analysis,single-crystal X-ray diffraction analysis,fluorescent spectrum and TGA.The crystal structure is of monoclinic,space group P2(1)/n,a=1.104 18(13)nm,b=1.119 24(14)nm,c=1.573 45(18)nm,α=90(°),β=104.150(5)(°),γ=90(°),Mr=436.75,V=1.885 5(4) nm~3,Z=4,Dc=(1.539 mg·m~(-3)),F(000)=900,GOF=1.073,R_1=0.038 1,ωR_2=0.100 2.

Key concepts: Monoclinic crystal system, Diamondoid, Crystallography, Supramolecular chemistry, Crystal structure, Infrared spectroscopy, Triclinic crystal system, Single crystal

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Synthesis,Crystal Structure and Property of Three-dimensional Supramolecular Complex[Zn(C_(13)H_(14)N_2)(C_8H_4O_4)]_n·0.5nH_2O — Research Paper | ScholarLens