2003Dalian Qinggongye Xueyuan xuebaoRequires access

Synthesis of amphoteric copolymerric flocculant grafted on starch

Zhao Liu

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Abstract

This paper reports the investigation of the synthesis condition of amphoteric monomer and the rule of copolymerized grafting it on starch by using (NH4)2S2O8 as initiator. Experimental results indicate that the yield of amphoteric monomer is more than 98% under the condition: pH, 9~10;reaction temperature, 85?℃; reaction time, 5?h. The optimum variables of grafting ratio, grafting efficiency, and [η] of the copolymer are obtained at initiator concentration of 2.2?mmol/L,monomer dosage of 1.8/1(monomer/starch ),reaction temperature of 45?℃, and reaction time of 4?h.

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What this paper is about

This paper reports the investigation of the synthesis condition of amphoteric monomer and the rule of copolymerized grafting it on starch by using (NH4)2S2O8 as initiator. Experimental results indicate that the yield of amphoteric monomer is more than 98% under the condition: pH, 9~10;reaction temperature, 85?℃; reaction time, 5?h. The optimum variables of grafting ratio, grafting efficiency, and [η] of the copolymer are obtained at initiator concentration of 2.2?mmol/L,monomer dosage of 1.8/1(monomer/starch ),reaction temperature of 45?℃, and reaction time of 4?h.

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Available abstract

This paper reports the investigation of the synthesis condition of amphoteric monomer and the rule of copolymerized grafting it on starch by using (NH4)2S2O8 as initiator. Experimental results indicate that the yield of amphoteric monomer is more than 98% under the condition: pH, 9~10;reaction temperature, 85?℃; reaction time, 5?h. The optimum variables of grafting ratio, grafting efficiency, and [η] of the copolymer are obtained at initiator concentration of 2.2?mmol/L,monomer dosage of 1.8/1(monomer/starch ),reaction temperature of 45?℃, and reaction time of 4?h.

Key concepts: Monomer, Grafting, Starch, Copolymer, Yield (engineering), Polymer chemistry, Chemistry, Flocculation

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