Analysis of ~(97)Tc Spike by Negative Thermal Ionization Mass Spectrometry
Liu Zhao
Abstract
Liu Zhao
Abstract
97Tc spike produced by our laboratory was analyzed by negative thermal ionization mass spectrometry(NTIMS).Equal-probability model was used for correction of isotope ratio measurements.The isotope ratio of 97Tc spike was measured with the expanded uncertainty of 1.3%(K=2).97Tc concentration was also determined by isotope dilution mass spectrometry(IDMS) with the expanded uncertainty of 2.12%(K=2).
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97Tc spike produced by our laboratory was analyzed by negative thermal ionization mass spectrometry(NTIMS).Equal-probability model was used for correction of isotope ratio measurements.The isotope ratio of 97Tc spike was measured with the expanded uncertainty of 1.3%(K=2).97Tc concentration was also determined by isotope dilution mass spectrometry(IDMS) with the expanded uncertainty of 2.12%(K=2).
Key concepts: Thermal ionization mass spectrometry, Mass spectrometry, Isotope dilution, Isotope, Thermal ionization, Chemistry, Analytical Chemistry (journal), Ionization