2003•Analytical LaboratoryRequires access

Studies of polarographic adsorptive wave of antimony(III)-rutin-selenium(IV) system

Huang Mei

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Abstract

In a chloroactate buffer solution(pH 3.2) containing Se(Ⅳ), a sensitive polarographic adsorptive wave of antimony(Ⅲ) rutin complex was obtaind by using single sweep polarography. The prensence of selenium(Ⅳ) could enhance the sensitivity. The peak potential appear at -0.33 V(vs.SCE). The peak height was linearly proportional to the concentration of antimony(Ⅲ) over a range of 1.6×10 -9 ~5×10 -6 mol/L with a detection limit of 4×10 -10 mol/L. The properties of polarographic wave and the electrode reaction mechanism were discussed. The method was used to determination of antimony in zinc alloys.

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In a chloroactate buffer solution(pH 3.2) containing Se(Ⅳ), a sensitive polarographic adsorptive wave of antimony(Ⅲ) rutin complex was obtaind by using single sweep polarography. The prensence of selenium(Ⅳ) could enhance the sensitivity. The peak potential appear at -0.33 V(vs.SCE). The peak height was linearly proportional to the concentration of antimony(Ⅲ) over a range of 1.6×10 -9 ~5×10 -6 mol/L with a detection limit of 4×10 -10 mol/L. The properties of polarographic wave and the electrode reaction mechanism were discussed. The method was used to determination of antimony in zinc alloys.

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Available abstract

In a chloroactate buffer solution(pH 3.2) containing Se(Ⅳ), a sensitive polarographic adsorptive wave of antimony(Ⅲ) rutin complex was obtaind by using single sweep polarography. The prensence of selenium(Ⅳ) could enhance the sensitivity. The peak potential appear at -0.33 V(vs.SCE). The peak height was linearly proportional to the concentration of antimony(Ⅲ) over a range of 1.6×10 -9 ~5×10 -6 mol/L with a detection limit of 4×10 -10 mol/L. The properties of polarographic wave and the electrode reaction mechanism were discussed. The method was used to determination of antimony in zinc alloys.

Key concepts: Polarography, Antimony, Chemistry, Detection limit, Rutin, Selenium, Inorganic chemistry, Peak current

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