2009Huanjing jiance guanli yu jishuRequires access

Cadmium in Soil Determination by Hydride Generation-Atomic Fluorescence Spectrometry

Xingyang Wang

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Abstract

The cadmium in soil was determinated by hydride generation-atomic fluorescence spectrometry.It was discussed on the interference of coexisting elements and elimination method.The optimized tests produced the following results: a good linearity in range from 0 μg/L to 120 μg/L;detection limit 0.003 mg/kg(by 0.600 g sample,volume to 45 mL);RSD of standard soil sample ≤3.7%;spiked recovery 94.8%,and the result was equaled to the soil standard sample value measured by graphite furnace atomic absorption spectrophotometry.

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The cadmium in soil was determinated by hydride generation-atomic fluorescence spectrometry.It was discussed on the interference of coexisting elements and elimination method.The optimized tests produced the following results: a good linearity in range from 0 μg/L to 120 μg/L;detection limit 0.003 mg/kg(by 0.600 g sample,volume to 45 mL);RSD of standard soil sample ≤3.7%;spiked recovery 94.8%,and the result was equaled to the soil standard sample value measured by graphite furnace atomic absorption spectrophotometry.

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Available abstract

The cadmium in soil was determinated by hydride generation-atomic fluorescence spectrometry.It was discussed on the interference of coexisting elements and elimination method.The optimized tests produced the following results: a good linearity in range from 0 μg/L to 120 μg/L;detection limit 0.003 mg/kg(by 0.600 g sample,volume to 45 mL);RSD of standard soil sample ≤3.7%;spiked recovery 94.8%,and the result was equaled to the soil standard sample value measured by graphite furnace atomic absorption spectrophotometry.

Key concepts: Cadmium, Hydride, Atomic absorption spectroscopy, Detection limit, Chemistry, Graphite furnace atomic absorption, Analytical Chemistry (journal), Mass spectrometry

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