2007Thermosetting ResinRequires access

Progress of ambient temperature crosslinking technology of waterborne polyurethane

HU Jian-qing

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Abstract

The new progress of crosslinking modification technology at ambient temperature of waterborne polyurethane had been reviewed in this paper.The crosslinking systems and their mechanism were summarized in detail,including 9 kinds of crosslinking methods at ambient temperature,such as: 1 crosslinking between carbonyl and hydrazide group;2 crosslinking by Michael addition reaction;3 crosslinking of isocyanurate group;4 crosslinking between aziridinyl group or its derivative and carbonyl group;5 crosslinking of cycllic carbonates with amine;6 crosslinking by self oxidation of double bond in drying oil dispersed in waterborne polyurethane system;7 crosslinking between cycloaliphatic diepoxide and carbonyl group;8 crosslinking by chelation of metal salts with carbonyl and/or sulfo group and 9 hydrolytic condensation crosslinking of silylated polyurethane dispersions

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The new progress of crosslinking modification technology at ambient temperature of waterborne polyurethane had been reviewed in this paper.The crosslinking systems and their mechanism were summarized in detail,including 9 kinds of crosslinking methods at ambient temperature,such as: 1 crosslinking between carbonyl and hydrazide group;2 crosslinking by Michael addition reaction;3 crosslinking of isocyanurate group;4 crosslinking between aziridinyl group or its derivative and carbonyl group;5 crosslinking of cycllic carbonates with amine;6 crosslinking by self oxidation of double bond in drying oil dispersed in waterborne polyurethane system;7 crosslinking between cycloaliphatic diepoxide and carbonyl group;8 crosslinking by chelation of metal salts with carbonyl and/or sulfo group and 9 hydrolytic condensation crosslinking of silylated polyurethane dispersions

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Available abstract

The new progress of crosslinking modification technology at ambient temperature of waterborne polyurethane had been reviewed in this paper.The crosslinking systems and their mechanism were summarized in detail,including 9 kinds of crosslinking methods at ambient temperature,such as: 1 crosslinking between carbonyl and hydrazide group;2 crosslinking by Michael addition reaction;3 crosslinking of isocyanurate group;4 crosslinking between aziridinyl group or its derivative and carbonyl group;5 crosslinking of cycllic carbonates with amine;6 crosslinking by self oxidation of double bond in drying oil dispersed in waterborne polyurethane system;7 crosslinking between cycloaliphatic diepoxide and carbonyl group;8 crosslinking by chelation of metal salts with carbonyl and/or sulfo group and 9 hydrolytic condensation crosslinking of silylated polyurethane dispersions

Key concepts: Polyurethane, Materials science, Polymer chemistry, Double bond, Amine gas treating, Hydrolysis, Hydrazide, Carbonyl group

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