2009•Textile AuxiliariesRequires access

Long carbon chain quaternary ammonium salt modification of cellulose fiber and its dyeing property

Haibo Wang

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Abstract

The cationic grafting agent TQBET,containing dual reactive groups,tri-quaternary ammonium salt and long chain structure,was synthesized by cyanuric trichloride,N,N-dimethly propane diamine,chloroethyl-amine chloride salt,dodeca-tertiary amine and epichlorohydrin.It was applied in grafting modification and dyeing of cotton fabric.The results showed that the cotton fabric modified with TQBET could be applied in self-free dyeing with reactive dyes.The exhaustion rate,fixation rate and color fastness of the salt-free dyeing of modi-fied fabric were better than those of the traditional dyed fabric.The availability of the dye was improved and the levelness of the modified fabric was also significantly improved.

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What this paper is about

The cationic grafting agent TQBET,containing dual reactive groups,tri-quaternary ammonium salt and long chain structure,was synthesized by cyanuric trichloride,N,N-dimethly propane diamine,chloroethyl-amine chloride salt,dodeca-tertiary amine and epichlorohydrin.It was applied in grafting modification and dyeing of cotton fabric.The results showed that the cotton fabric modified with TQBET could be applied in self-free dyeing with reactive dyes.The exhaustion rate,fixation rate and color fastness of the salt-free dyeing of modi-fied fabric were better than those of the traditional dyed fabric.The availability of the dye was improved and the levelness of the modified fabric was also significantly improved.

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Available abstract

The cationic grafting agent TQBET,containing dual reactive groups,tri-quaternary ammonium salt and long chain structure,was synthesized by cyanuric trichloride,N,N-dimethly propane diamine,chloroethyl-amine chloride salt,dodeca-tertiary amine and epichlorohydrin.It was applied in grafting modification and dyeing of cotton fabric.The results showed that the cotton fabric modified with TQBET could be applied in self-free dyeing with reactive dyes.The exhaustion rate,fixation rate and color fastness of the salt-free dyeing of modi-fied fabric were better than those of the traditional dyed fabric.The availability of the dye was improved and the levelness of the modified fabric was also significantly improved.

Key concepts: Dyeing, Epichlorohydrin, Cationic polymerization, Cyanuric chloride, Reactive dye, Salt (chemistry), Cellulose, Grafting

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Long carbon chain quaternary ammonium salt modification of cellulose fiber and its dyeing property — Research Paper | ScholarLens