2009•Journal of Hengyang Normal UniversityRequires access

Hydrothermal Synthesis and Crystal Structure of a New Compound [(C_(10)H_(10)N_2)(C_(10)H_9N_2)(PMo_(12)O_(40))]·(C_(10)H_8N_2)_2·7H_2O

Zou Jian-ling

Abstract

A new compound [(C10H10N2)(C10H9N2)(PMo12O40)]·(C10H8N2)2·7H2O was obtained by means of hydrothermal way.It was characterized as crystallizing in the monoclinic space group P2(1)/c,with a= 1.87700(16) nm,b= 1.40329(12) nm,c= 2.6543(2) nm,β= 105.4510(10)°,V=6.7386(10) nm3,Dc=2.539g/cm3,Z=2,Mr = 2576.12,μ(MoKα) = 2.290 mm-1,F(000)= 4960,R1=0.0548,wR2 =0.1342.The crystal structure shows that the title compound consists of one polyoxomatelate(PMo12O403-) with the Keggin structure,two 4,4′-bipyridine cations,two 4,4′-bipyridine molecules and seven water molecules.There are hydrogen bonds in the title compound.

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Key concepts: Monoclinic crystal system, Crystallography, Molecule, Hydrothermal circulation, Crystal structure, Hydrothermal synthesis, Hydrogen bond, Crystal (programming language)