2010•Journal of Minjiang UniversityRequires access

Hydrothermal synthesis and crystal structure of a novel complex (C_5N_2H_6)_3(C_5N_2H_7)_3[(PO_4)Mo_(12)O_(36)]·2H_2O

Jiang Li-fang

Abstract

The title compound( ( C5N2H6) 3 ( C5N2H7) 3 [( PO4) Mo12 O36]·2H2O,Mr = 2403. 00) is synthesized by hydrothermal reaction. It crystallizes in a mono-clini system with space group P2( 1) /n and unit cell parameters a = 13. 316( 3),b = 22. 414( 5),c = 20. 063( 4),α = 90. 00( 4) °,β = 100. 743 ( 3) °,γ = 90. 00°,V =5883( 2) 3,Z =4,Dc =2. 713 Mg/m3,μ( MoKα) =2. 608mm-1,F000 =4604,R = 0. 0596,wR = 0. 1345,GoF = 1. 042. The structure of title compound consists of a [( PO4) Mo12O36]3 -cluster,which is connected by hydrogen bond through the O atoms with α-Pyridylamine to form a 3-di-mension structure with water molecular and α-Pyridylamine fulfilling.

About this research paper

What this paper is about

Why it matters

A significance statement is not available in the OpenAlex record.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

Key concepts: Crystallography, Hydrothermal circulation, Cluster (spacecraft), Hydrogen bond, Crystal structure, Hydrothermal synthesis, Chemistry, Group (periodic table)