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Nitration of Tetraacetyldibenzylhexaazaisowutzitane with Phase Transfer Catalysts

Pang Si-ping

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Abstract

The nitration of tetraacetyldibenzylhexaazaisowutzitane by CAN and NaNO_2 in chloroform in the presence of phase transfer catalysts was kept for 8 hours at 40 ℃. The remained benzyl groups were nitrated successfully and the corresponding products-tetraacetyldinitrohexaazaisowutzitane was obtained with a yield of 66%. The mechanism of the nitration of N-benzyl group by CAN in the presence of phase transfer catalysts is discussed.

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What this paper is about

The nitration of tetraacetyldibenzylhexaazaisowutzitane by CAN and NaNO_2 in chloroform in the presence of phase transfer catalysts was kept for 8 hours at 40 ℃. The remained benzyl groups were nitrated successfully and the corresponding products-tetraacetyldinitrohexaazaisowutzitane was obtained with a yield of 66%. The mechanism of the nitration of N-benzyl group by CAN in the presence of phase transfer catalysts is discussed.

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Available abstract

The nitration of tetraacetyldibenzylhexaazaisowutzitane by CAN and NaNO_2 in chloroform in the presence of phase transfer catalysts was kept for 8 hours at 40 ℃. The remained benzyl groups were nitrated successfully and the corresponding products-tetraacetyldinitrohexaazaisowutzitane was obtained with a yield of 66%. The mechanism of the nitration of N-benzyl group by CAN in the presence of phase transfer catalysts is discussed.

Key concepts: Nitration, Catalysis, Chemistry, Phase (matter), Yield (engineering), Chloroform, Organic chemistry, Phase-transfer catalyst

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