SYNTHESIS AND CHARACTERIZATION OF U(VI) AND Th(IV) COMPLEXES WITH o-VANILLIN-p-PHENYLENEDIAMINE
Bi Cai
Abstract
Bi Cai
Abstract
Two new solid complexes of uranyl nitrate and thorium nitrate with bis Shiff base o vanillin p phenylenediamine (L) have been synthesized and characterized by elemental analysis, IR, UV, DTA TG and molar conductance. The compositions of the complexes are confirmed to be [UO 2LNO 3]NO 3 and [ThL(NO 3) 2](NO 3) 2. Some properties of the complexes are studied.
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Two new solid complexes of uranyl nitrate and thorium nitrate with bis Shiff base o vanillin p phenylenediamine (L) have been synthesized and characterized by elemental analysis, IR, UV, DTA TG and molar conductance. The compositions of the complexes are confirmed to be [UO 2LNO 3]NO 3 and [ThL(NO 3) 2](NO 3) 2. Some properties of the complexes are studied.
Key concepts: Chemistry, Thorium, Nuclear chemistry, Elemental analysis, Uranyl nitrate, Nitrate, Uranyl, Uranium