2012Transactions of China Pulp and PaperRequires access

Preparation and Characterization of Surface Sizing Agent of Chitosan Graft Styrene-butyl Acrylate Copolymer

Wang Xi-feng

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Abstract

The chitosan graft copolymer used as surface sizing agent was prepared by soap-free emulsion polymerization with styrene(St),butylacrylate(BA),N-hydroxymethyl acrylamide(HMAM) and dimethyl diallyl ammonium chloride(DMDAAC) as major monomers in oxidation-reduction initiator system.The copolymer was characterized with infrared spectrum(FT-IR),static contact angle and SEM.The optimum synthesis conditions are as follows: m(monomer)/m(chitosan)=25,m(St)/m(BA)=2.5,m(KPS)/m(chitosan)=3.0,m(FeSO4)/m(H2O2)=0.03,and HMAM dosage 6%.The application experiment results demonstrated that when the dosage of surface sizing agent is 0.4%,the paper can achieve the best performance.

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What this paper is about

The chitosan graft copolymer used as surface sizing agent was prepared by soap-free emulsion polymerization with styrene(St),butylacrylate(BA),N-hydroxymethyl acrylamide(HMAM) and dimethyl diallyl ammonium chloride(DMDAAC) as major monomers in oxidation-reduction initiator system.The copolymer was characterized with infrared spectrum(FT-IR),static contact angle and SEM.The optimum synthesis conditions are as follows: m(monomer)/m(chitosan)=25,m(St)/m(BA)=2.5,m(KPS)/m(chitosan)=3.0,m(FeSO4)/m(H2O2)=0.03,and HMAM dosage 6%.The application experiment results demonstrated that when the dosage of surface sizing agent is 0.4%,the paper can achieve the best performance.

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Available abstract

The chitosan graft copolymer used as surface sizing agent was prepared by soap-free emulsion polymerization with styrene(St),butylacrylate(BA),N-hydroxymethyl acrylamide(HMAM) and dimethyl diallyl ammonium chloride(DMDAAC) as major monomers in oxidation-reduction initiator system.The copolymer was characterized with infrared spectrum(FT-IR),static contact angle and SEM.The optimum synthesis conditions are as follows: m(monomer)/m(chitosan)=25,m(St)/m(BA)=2.5,m(KPS)/m(chitosan)=3.0,m(FeSO4)/m(H2O2)=0.03,and HMAM dosage 6%.The application experiment results demonstrated that when the dosage of surface sizing agent is 0.4%,the paper can achieve the best performance.

Key concepts: Copolymer, Chitosan, Butyl acrylate, Monomer, Styrene, Polymer chemistry, Acrylamide, Contact angle

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