ScholarLens Back to search
2007•Guangzhou ChemistryRequires access

Synthesis of Ketals of Ethyl Acetoacetate Catalyzed by Activated Carbon Supported SnCl_4·5H_2O under Microwave Irradiation

Xian‐You Yuan

Open publisher page 0 citations

Abstract

Two ketals were synthesized from ethyl acetoacetate with ethylene glycol and 1,2-propanediol using activated carbon supported SnCl4·5H2O(SnCl4?5H2O/C) as catalysts without solvent under microwave irradiation.Under the optimum reaction conditions(SnCl4·5H2O/C(loaded amount 20%) 0.1 g),ethyl acetoacetate 5 mL,ethylene glycol 6 mL,microwave power 600 W,microwave irradiation time 2.5 min,the yield of ketal was 81.6%.The products were characterized by IR.

About this research paper

What this paper is about

Two ketals were synthesized from ethyl acetoacetate with ethylene glycol and 1,2-propanediol using activated carbon supported SnCl4·5H2O(SnCl4?5H2O/C) as catalysts without solvent under microwave irradiation.Under the optimum reaction conditions(SnCl4·5H2O/C(loaded amount 20%) 0.1 g),ethyl acetoacetate 5 mL,ethylene glycol 6 mL,microwave power 600 W,microwave irradiation time 2.5 min,the yield of ketal was 81.6%.The products were characterized by IR.

Why it matters

A significance statement is not available in the OpenAlex record.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

Two ketals were synthesized from ethyl acetoacetate with ethylene glycol and 1,2-propanediol using activated carbon supported SnCl4·5H2O(SnCl4?5H2O/C) as catalysts without solvent under microwave irradiation.Under the optimum reaction conditions(SnCl4·5H2O/C(loaded amount 20%) 0.1 g),ethyl acetoacetate 5 mL,ethylene glycol 6 mL,microwave power 600 W,microwave irradiation time 2.5 min,the yield of ketal was 81.6%.The products were characterized by IR.

Key concepts: Chemistry, Ethyl acetoacetate, Ethylene glycol, Catalysis, Microwave irradiation, Yield (engineering), Solvent, Nuclear chemistry

Related papers

Related paper 1Related paper 2Related paper 3
Back to paper searchBrowse research topicsOriginal source
Synthesis of Ketals of Ethyl Acetoacetate Catalyzed by Activated Carbon Supported SnCl_4·5H_2O under Microwave Irradiation — Research Paper | ScholarLens