Synthesis and Crystal Structure of {[Ag(dps)ClO_4]·H_2O}_n Complex with One-Dimensional Chain Structure Construed by V-Ligand

The complex was synthesized with 4,4′-Dipyridyl Sulfide and Ag(ClO4) by the hydrothermal method.The result shows that the complex crystallizes in monoclinic,space group C2/c with a=1.3602(2)nm,b=0.99 188(16)nm,c=2.0 516(3)nm,β=102.385(2)°,V=2 703.5(7) A3,Z=8,thefinal.R=0.0 486,wR=0.1 072.The coordination environment of Ag(Ⅰ)ligand with two N atoms,and come into an infinite one-dimensional(1D) chain structure.These coordination polymer chains are further organized by two different intermolecular hydrogen bonds(C-H…O and O-H…O) and π-π interactions to afford a 3D supermolecular structure.