2014Industrial & Engineering Chemistry ResearchRequires access

Facile Synthesis of Mesoporous Zeolite Y with Improved Catalytic Performance for Heavy Oil Fluid Catalytic Cracking

Junsu Jin, Chaoyun Peng, Jiujiang Wang, Hongtao Liu, Hongtao Liu, Xionghou Gao, Honghai Liu, Honghai Liu, Chunyan Xu

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Abstract

A facile and direct approach for the synthesis of mesoporous zeolite Y by using [(CH 3 O) 3 SiC 3 H 6 N(CH 3 ) 2 -C 18 H 37 ]Cl as template is presented. Under the basic condition of the Y synthesis system, (CH 3 O) 3 Si– bonds hydrolyze to −Si–OH, and yield −Si–O–Al– and −Si–O–Si– linkages that anchor the template in zeolite framework. Afterward, micelles formed by −C 18 H 37 lead to the formation of mesoporosity within zeolite Y crystals. This material, which introduces intracrystalline mesoporosity into zeolite Y, shows superior catalytic performance when used in heavy oil catalytic cracking.

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What this paper is about

A facile and direct approach for the synthesis of mesoporous zeolite Y by using [(CH 3 O) 3 SiC 3 H 6 N(CH 3 ) 2 -C 18 H 37 ]Cl as template is presented. Under the basic condition of the Y synthesis system, (CH 3 O) 3 Si– bonds hydrolyze to −Si–OH, and yield −Si–O–Al– and −Si–O–Si– linkages that anchor the template in zeolite framework. Afterward, micelles formed by −C 18 H 37 lead to the formation of mesoporosity within zeolite Y crystals. This material, which introduces intracrystalline mesoporosity into zeolite Y, shows superior catalytic performance when used in heavy oil catalytic cracking.

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Available abstract

A facile and direct approach for the synthesis of mesoporous zeolite Y by using [(CH 3 O) 3 SiC 3 H 6 N(CH 3 ) 2 -C 18 H 37 ]Cl as template is presented. Under the basic condition of the Y synthesis system, (CH 3 O) 3 Si– bonds hydrolyze to −Si–OH, and yield −Si–O–Al– and −Si–O–Si– linkages that anchor the template in zeolite framework. Afterward, micelles formed by −C 18 H 37 lead to the formation of mesoporosity within zeolite Y crystals. This material, which introduces intracrystalline mesoporosity into zeolite Y, shows superior catalytic performance when used in heavy oil catalytic cracking.

Key concepts: Zeolite, Mesoporous material, Catalysis, Fluid catalytic cracking, Cracking, Hydrolysis, Yield (engineering), Materials science

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