Facile Synthesis of Mesoporous Zeolite Y with Improved Catalytic Performance for Heavy Oil Fluid Catalytic Cracking
Junsu Jin, Chaoyun Peng, Jiujiang Wang, Hongtao Liu, Hongtao Liu, Xionghou Gao, Honghai Liu, Honghai Liu, Chunyan Xu
Abstract
Junsu Jin, Chaoyun Peng, Jiujiang Wang, Hongtao Liu, Hongtao Liu, Xionghou Gao, Honghai Liu, Honghai Liu, Chunyan Xu
Abstract
A facile and direct approach for the synthesis of mesoporous zeolite Y by using [(CH 3 O) 3 SiC 3 H 6 N(CH 3 ) 2 -C 18 H 37 ]Cl as template is presented. Under the basic condition of the Y synthesis system, (CH 3 O) 3 Si– bonds hydrolyze to −Si–OH, and yield −Si–O–Al– and −Si–O–Si– linkages that anchor the template in zeolite framework. Afterward, micelles formed by −C 18 H 37 lead to the formation of mesoporosity within zeolite Y crystals. This material, which introduces intracrystalline mesoporosity into zeolite Y, shows superior catalytic performance when used in heavy oil catalytic cracking.
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A facile and direct approach for the synthesis of mesoporous zeolite Y by using [(CH 3 O) 3 SiC 3 H 6 N(CH 3 ) 2 -C 18 H 37 ]Cl as template is presented. Under the basic condition of the Y synthesis system, (CH 3 O) 3 Si– bonds hydrolyze to −Si–OH, and yield −Si–O–Al– and −Si–O–Si– linkages that anchor the template in zeolite framework. Afterward, micelles formed by −C 18 H 37 lead to the formation of mesoporosity within zeolite Y crystals. This material, which introduces intracrystalline mesoporosity into zeolite Y, shows superior catalytic performance when used in heavy oil catalytic cracking.
Key concepts: Zeolite, Mesoporous material, Catalysis, Fluid catalytic cracking, Cracking, Hydrolysis, Yield (engineering), Materials science