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2015•Journal of Structural ChemistryRequires access

Crystal structure of copper(I) thiosemicarbazone complex [CuI(PPh3)(catsc)]

E. Shahsavani, N. Feizi, Václav Eigner, Michal Dušek, Aliakbar Dehno Khalaji

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Abstract

In this paper, we report the preparation of a four-coordinated copper(I) thiosemicarbazone complex [CuI(PPh 3 )(catsc)] from the reaction of PPh 3 and catsc (3-phenylpropenalthiosemicarbazone) with CuI. The synthesized complex is characterized by elemental analyses (CHNS) and FT-IR spectroscopy. The crystal structure of [CuI(PPh 3 )(catsc)] is investigated by single crystal X-ray diffraction. The catsc coordinates to the copper(I) ion as a bidentate ligand via the N and S atoms. The complex has a distorted tetrahedral coordination geometry.

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What this paper is about

In this paper, we report the preparation of a four-coordinated copper(I) thiosemicarbazone complex [CuI(PPh 3 )(catsc)] from the reaction of PPh 3 and catsc (3-phenylpropenalthiosemicarbazone) with CuI. The synthesized complex is characterized by elemental analyses (CHNS) and FT-IR spectroscopy. The crystal structure of [CuI(PPh 3 )(catsc)] is investigated by single crystal X-ray diffraction. The catsc coordinates to the copper(I) ion as a bidentate ligand via the N and S atoms. The complex has a distorted tetrahedral coordination geometry.

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Available abstract

In this paper, we report the preparation of a four-coordinated copper(I) thiosemicarbazone complex [CuI(PPh 3 )(catsc)] from the reaction of PPh 3 and catsc (3-phenylpropenalthiosemicarbazone) with CuI. The synthesized complex is characterized by elemental analyses (CHNS) and FT-IR spectroscopy. The crystal structure of [CuI(PPh 3 )(catsc)] is investigated by single crystal X-ray diffraction. The catsc coordinates to the copper(I) ion as a bidentate ligand via the N and S atoms. The complex has a distorted tetrahedral coordination geometry.

Key concepts: Copper, Semicarbazone, Crystallography, Denticity, Crystal structure, Chemistry, Coordination geometry, Solid-state physics

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