ScholarLens Back to search
1963•OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)Requires access

ON RADICAL INITIATED CHAIN OXIDATION OF IRON(II) IN AIR SATURATED ACID SOLUTIONS CONTAINING ALCHOHOLS. III. CHAIN PROCESSES IN GAMMA IRRADIATED SOLUTIONS CONTAINING C$sub 2$H$sub 5$OH

Liliana Stolarczyk

Open publisher page 0 citations

Abstract

The G(Fe/sup 3+/) values were measured in air-saturated aqueous solutions of 2.5 x 10/sup -4/ M Fe/sup 2+/, 0.4 M H/sub 2/SO/sub 4/, and 0.5 to 10 x 10/sup -4/ M C/sub 2/H/sub 5/OH after gamma irradiation. An inflection point on the curve of the relation between G(Fe/sup 3+/) and the concentration of C/sub 2/H/sub 5/OH was observed. The results are qualitatively explained as the competition between various chain mechanisms of iron oxidation and various possible chain breaking reactions. (auth)

About this research paper

What this paper is about

The G(Fe/sup 3+/) values were measured in air-saturated aqueous solutions of 2.5 x 10/sup -4/ M Fe/sup 2+/, 0.4 M H/sub 2/SO/sub 4/, and 0.5 to 10 x 10/sup -4/ M C/sub 2/H/sub 5/OH after gamma irradiation. An inflection point on the curve of the relation between G(Fe/sup 3+/) and the concentration of C/sub 2/H/sub 5/OH was observed. The results are qualitatively explained as the competition between various chain mechanisms of iron oxidation and various possible chain breaking reactions. (auth)

Why it matters

A significance statement is not available in the OpenAlex record.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

The G(Fe/sup 3+/) values were measured in air-saturated aqueous solutions of 2.5 x 10/sup -4/ M Fe/sup 2+/, 0.4 M H/sub 2/SO/sub 4/, and 0.5 to 10 x 10/sup -4/ M C/sub 2/H/sub 5/OH after gamma irradiation. An inflection point on the curve of the relation between G(Fe/sup 3+/) and the concentration of C/sub 2/H/sub 5/OH was observed. The results are qualitatively explained as the competition between various chain mechanisms of iron oxidation and various possible chain breaking reactions. (auth)

Key concepts: Chemistry, Radiation chemistry, Aqueous solution, Irradiation, Radical, Cobalt-60, Radiolysis, Chain (unit)

Related papers

Related paper 1Related paper 2Related paper 3
Back to paper searchBrowse research topicsOriginal source
ON RADICAL INITIATED CHAIN OXIDATION OF IRON(II) IN AIR SATURATED ACID SOLUTIONS CONTAINING ALCHOHOLS. III. CHAIN PROCESSES IN GAMMA IRRADIATED SOLUTIONS CONTAINING C$sub 2$H$sub 5$OH — Research Paper | ScholarLens