2016•Dalton TransactionsRequires access

Ionic self-assembly affords mesoporous ionic networks by crosslinking linear polyviologens with polyoxometalate clusters

Guojian Chen, Wei Hou, Jing Li, Xiaochen Wang, Yu Zhou, Jun Wang

Abstract

Ionic-bonded mesoporous ionic networks were prepared by the ionic self-assembly of polyoxometalate (POM) clusters with linear cationic polyviologens in water. The POM-enriched PMIN-2(V) possesses a high surface area up to 120 m(2) g(-1), exhibiting superior non-noble metal heterogeneous catalytic performance in the ambient aerobic selective oxidation of 5-hydroxymethylfurfural.

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Key concepts: Polyoxometalate, Mesoporous material, Ionic bonding, Ionic liquid, Cationic polymerization, Materials science, Catalysis, Chemical engineering