2010•Journal of Scientific & Industrial ResearchOpen access

Adsorption of pyridine on post-crosslinked fiber

Yanli Zhang, Li Dongguang

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Abstract

A novel post-crosslinked fiber, which was prepared by cross-linking base fiber with monochlorodimethylether using Friedel-Crafts reaction, has excellent adsorption capacity for pyridine. Adsorption equilibrium data could be well fitted by Freundlich model. Adsorption of pyridine on adsorbent was physical adsorption and lower temperature was favorable to exothermic physisorption process. Adsorption capacities calculated by pseudo-second-order rate model were close to the values actually measured at lower temperatures.

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A novel post-crosslinked fiber, which was prepared by cross-linking base fiber with monochlorodimethylether using Friedel-Crafts reaction, has excellent adsorption capacity for pyridine. Adsorption equilibrium data could be well fitted by Freundlich model. Adsorption of pyridine on adsorbent was physical adsorption and lower temperature was favorable to exothermic physisorption process. Adsorption capacities calculated by pseudo-second-order rate model were close to the values actually measured at lower temperatures.

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Available abstract

A novel post-crosslinked fiber, which was prepared by cross-linking base fiber with monochlorodimethylether using Friedel-Crafts reaction, has excellent adsorption capacity for pyridine. Adsorption equilibrium data could be well fitted by Freundlich model. Adsorption of pyridine on adsorbent was physical adsorption and lower temperature was favorable to exothermic physisorption process. Adsorption capacities calculated by pseudo-second-order rate model were close to the values actually measured at lower temperatures.

Key concepts: Physisorption, Adsorption, Pyridine, Exothermic reaction, Freundlich equation, Fiber, Chemistry, Exothermic process

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