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2010•Russian Journal of Organic ChemistryRequires access

Condensation of Trifluoromethanesulfonamide with Paraformaldehyde and Oxamide

V. I. Meshcheryakov, Mikhail Yu. Moskalik, I. Starke, Bagrat А. Shainyan

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Abstract

Depending on the conditions, three-component condensation of trifluoromethanesulfonamide with paraformaldehyde and oxamide led to the formation of linear products, N -mono- and N , N’ -bis[(trifluoromethylsulfonyl)aminomethyl]oxamide, bis[(trifluoromethylsulfonyl)aminomethyl] ethanedioate, as well as of hydrolysis and cyclization product, N -(4,5-dioxo-1,3-oxazolidin-3-ylmethyl)trifluoromethanesulfonamide.

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What this paper is about

Depending on the conditions, three-component condensation of trifluoromethanesulfonamide with paraformaldehyde and oxamide led to the formation of linear products, N -mono- and N , N’ -bis[(trifluoromethylsulfonyl)aminomethyl]oxamide, bis[(trifluoromethylsulfonyl)aminomethyl] ethanedioate, as well as of hydrolysis and cyclization product, N -(4,5-dioxo-1,3-oxazolidin-3-ylmethyl)trifluoromethanesulfonamide.

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Available abstract

Depending on the conditions, three-component condensation of trifluoromethanesulfonamide with paraformaldehyde and oxamide led to the formation of linear products, N -mono- and N , N’ -bis[(trifluoromethylsulfonyl)aminomethyl]oxamide, bis[(trifluoromethylsulfonyl)aminomethyl] ethanedioate, as well as of hydrolysis and cyclization product, N -(4,5-dioxo-1,3-oxazolidin-3-ylmethyl)trifluoromethanesulfonamide.

Key concepts: Oxamide, Paraformaldehyde, Chemistry, Condensation, Hydrolysis, Condensation reaction, Organic chemistry, Polymer chemistry

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