2003Journal of the American Ceramic SocietyRequires access

Yttrium Silicate Powders Produced by the Sol–Gel Method, Structural and Thermal Characterization

Damien Boyer, Brian Derby

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Abstract

Yttrium silicate (Y 2 SiO 5 ) powders of high purity have been synthesized using the sol–gel method. Alkoxide precursors were used with commercial tetraethyl orthosilicate as the silica source and yttrium propoxide synthesized from YCl 3 . Powders calcined from the xerogel showed submicrometer crystal sizes. These powders were sintered at temperatures <1300°C and are suitable for coating applications such as a thermal barrier system for SiC/SiC composites.

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Yttrium silicate (Y 2 SiO 5 ) powders of high purity have been synthesized using the sol–gel method. Alkoxide precursors were used with commercial tetraethyl orthosilicate as the silica source and yttrium propoxide synthesized from YCl 3 . Powders calcined from the xerogel showed submicrometer crystal sizes. These powders were sintered at temperatures <1300°C and are suitable for coating applications such as a thermal barrier system for SiC/SiC composites.

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Available abstract

Yttrium silicate (Y 2 SiO 5 ) powders of high purity have been synthesized using the sol–gel method. Alkoxide precursors were used with commercial tetraethyl orthosilicate as the silica source and yttrium propoxide synthesized from YCl 3 . Powders calcined from the xerogel showed submicrometer crystal sizes. These powders were sintered at temperatures <1300°C and are suitable for coating applications such as a thermal barrier system for SiC/SiC composites.

Key concepts: Tetraethyl orthosilicate, Yttrium, Orthosilicate, Materials science, Calcination, Sol-gel, Silicate, Alkoxide

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