2006•Journal of Coordination ChemistryRequires access

Monodentate imido coordination of 1,2-diaminobenzene to rhenium(V)

Thomas Gerber, D. Luzipo, Péter Mayer

Abstract

The complex trans-[Re(dab)Cl3(PPh3)2] (H2dab = 1,2-diaminobenzene) was prepared from the reaction of trans-[ReOCl3(PPh3)2] with H2dab in ethanol. The ligand dab is coordinated to the rhenium(V) centre only through a dianionic imido nitrogen to give a distorted octahedral coordination geometry around the metal ion.

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Key concepts: Rhenium, Chemistry, Denticity, Octahedron, Octahedral molecular geometry, Ligand (biochemistry), Nitrogen, Metal