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1995•Journal of the Chemical Society Dalton TransactionsRequires access

Dinuclear five-co-ordinate zinc complexes bridged by a phosphate monoester or an inorganic phosphate group

Harry Adams, Neil A. Bailey, David E. Fenton, Qing‐Yu He

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Abstract

Two dinuclear five-co-ordinated zinc complexes, derived from tris[(2-pyridyl)methyl] amine and bridged by a phosphate monoester or an inorganic phosphate group respectively, have been synthesized; the structures of the former has been established by X-Ray crystallography and shows the bridging mode of the phosphate to be syn–anti whereas in alkaline phosphatase it is syn–syn.

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Two dinuclear five-co-ordinated zinc complexes, derived from tris[(2-pyridyl)methyl] amine and bridged by a phosphate monoester or an inorganic phosphate group respectively, have been synthesized; the structures of the former has been established by X-Ray crystallography and shows the bridging mode of the phosphate to be syn–anti whereas in alkaline phosphatase it is syn–syn.

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Available abstract

Two dinuclear five-co-ordinated zinc complexes, derived from tris[(2-pyridyl)methyl] amine and bridged by a phosphate monoester or an inorganic phosphate group respectively, have been synthesized; the structures of the former has been established by X-Ray crystallography and shows the bridging mode of the phosphate to be syn–anti whereas in alkaline phosphatase it is syn–syn.

Key concepts: Phosphate, Zinc phosphate, Zinc, Inorganic phosphate, Chemistry, Amine gas treating, Tris, Alkaline phosphatase

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