2001•New Journal of ChemistryRequires access

First example of a vic-dioxime and its homo- and heteropentanuclear complexes containing a macrobicyclic moiety

Yaşar Gök, Ümmühan Ocak, Hasan Basri Şentürk

Abstract

The novel N,N′-substituted diaminoglyoxime (H2L) containing a diazadioxadithiacyclo macrobicycle has been synthesized from an aromatic primary amine containing a cryptand unit and (E,E)-dichloroglyoxime. The homopentanuclear nickel(II) and heteropentanuclear complexes of dioxime were obtained.

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Key concepts: Chemistry, Cryptand, Moiety, Amine gas treating, Nickel, Stereochemistry, Medicinal chemistry, Polymer chemistry